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Organosilicon Chemistry: 2 provides information pertinent to the fundamental aspects of organosilicon chemistry. This book discusses the organosilicon substituents in anionic rearrangements as well as examines the production of tetrakis allene from a large number of aliphatic and aromatic polyhalogenated compounds. Organized into 14 chapters, this book begins with an overview of the use of organosilyl groups as migrating substituents. This text then examines the development in the chemistry of organosilicon cyclic compounds. Other chapters consider the evidence supporting the intermediacy of silylenes and the general picture of the chemistry of organosilylenes. This book discusses as well the two major approaches for the silylation of polyhalogenated compounds, including the direct reaction of polyhalogenated compounds and the metalation or halogen-metal exchange between the halogenated aromatic compounds and organolithium reagents. The final chapter deals with the importance of hydrosilation. This book is a valuable resource for chemists, scientists, and research workers.
Thanks to the progress made in instruments and techniques, the methods in physical chemistry have developed rapidly over the past few decades, making them increasingly valuable for scientists of many disciplines. These two must-have volumes meet the needs of the scientific community for a thorough overview of all the important methods currently used. As such, this work bridges the gap between standard textbooks and review articles, covering a large number of methods, as well as the motivation behind their use. A uniform approach is adopted throughout both volumes, while the critical comparison of the advantages and disadvantages of each method makes this a valuable reference for physical chemists and other scientists working with these techniques.
Analytical Techniques in Environmental Chemistry 2 focuses on the establishment of analytical techniques in the management of compounds relative to their effects on health and nature. The book stresses that these analytical techniques are essential in order to cope with the problems arising from the utilization of these compounds. The selection contains the contributions of authors who have continuously performed studies on the analysis of organic and inorganic pollutants and monitoring strategies or case histories of compounds. These pieces focus on the role of analytical chemistry in the control of compounds, particularly if the compounds are seen to pose threat to health and the environment. The text presents studies on the determination of how these compounds can become pollutants, which are emphasized by the experiments and laboratory procedures mentioned in the book. Through research on hazardous compounds in different areas, the book manages to point out the differences of how these compounds can affect the environment and health. The text then proceeds by presenting various analytical techniques that could be employed to mitigate the hazardous nature of these compounds. The book is a reliable source of information for scholars and readers who are interested in studying how to control the hazardous effects of compounds both on health and the environment.
Organic Solid-State Chemistry–2 presents the solid state reactions in molecular crystals. This book discusses the correlations of the chemical structures of products from organic solid state reactions with the molecular packing in the reactant crystal structures. Organized into 10 chapters, this book begins with an overview of the molecular behavior after the chemical transition state. This text then examines the electron paramagnetic resonance methods, which offer many features in connection with the study of chemical reactions in which a paramagnetic species is a product or a reactant. Other chapters consider the interpretation of radiationless transitions, thermal reactions, and photochemical decompositions and rearrangements. The final chapter deals with the experimental results concerning electron and hole production in anthracene crystals, with emphasis on the relevance of these studies to the fundamental question of the nature of the excess electron states in these low mobility crystals. This book is a valuable resource for solid state chemists, photochemists, spectroscopists, scientists, and research workers.